The temperature and salt dependencies of absorption by liquid water (H₂O) and heavy water (D₂O) were
determined using a hyperspectral absorption and attenuation meter (WET Labs, AC-S). Sodium chloride
(NaCl) was used as a proxy for seawater salts. There was no significant temperature (ψₜ) or salt (ψₛ)
dependency of absorption...
By taking advantage of the electron pathway through the heme group in cytochrome c (CytoC) electrochemists
have built sensors based upon CytoC immobilized onto metal electrodes. Previous studies have shown that the
electron transfer rate through the protein is a function of the position of this heme group with respect...
A significant step transition between seasonally stratified and destratified hydrographic conditions occurred during an October 2008 cruise to the Florida Panhandle Shelf along a cross-shelf transect that was sampled before and after a cold front passed through the area. Meteorological measurements from nearby ocean and land-based stations characterized the event....
Plant wax lipids and lignin phenols are the two most common classes of molecular markers that are used to trace vascular plant-derived OM in the marine environment. However, their ¹³C and ¹⁴C compositions have not been directly compared, which can be used to constrain the flux and attenuation of terrestrial...
Hydrological optics has a rich history, playing a significant role in physical, chemical, and biological oceanography. The success over the last 30 years has provided oceanographers with a non-invasive means to study regional and global scale physical, chemical, and biological processes (Figure 1). The ability to map the color of...
Cadmium is a common impurity in phosphatic fertilizers and may contribute to soil Cd accumulation. Changes in total and bioavailable Cd burdens to agricultural soils and the potential for plant Cd accumulation resulting from fertilizer input was investigated. Three year field studies were conducted using three dose levels of cadmium-rich,...
Cadmium is a common impurity in phosphatic fertilizers and may contribute to soil Cd accumulation. Changes in total and bioavailable Cd burdens to agricultural soils and the potential for plant Cd accumulation resulting from fertilizer input was investigated. Three year field studies were conducted using three dose levels of cadmium-rich,...
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levels for the
nitrogen needs for the soil type, irrigation practices, and crops to be grown at
each
Recently, Duke and Jenkins have studied a certain family of modular forms fk,m, that form a natural basis of the space of weakly holomorphic modular forms of weight k on SL2(Z). In particular, they prove that for all but at most [k/12] + 1 values of m, the zeros of...
An upscaled elliptic-parabolic system of partial differential equations
describing the multiscale flow of a single-phase incompressible fluid and
transport of a dissolved chemical by advection and diffusion through a heterogeneous
porous medium is developed without the usual assumptions of scale
separation. After a review of homogenization results for the traditional...
Cadmium is a common impurity in phosphatic fertilizers and may contribute to soil Cd accumulation. Changes in total and bioavailable Cd burdens to agricultural soils and the potential for plant Cd accumulation resulting from fertilizer input was investigated. Three year field studies were conducted using three dose levels of cadmium-rich,...
Contamination of newly planted bermudagrass (Cynodon spp.) varieties by undesirable off-type bermudagrass genotypes is an
ever increasing concern for turf managers because selective control options are limited. In 2009, a sethoxydim {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one} tolerant bermudagrass genotype (93-175) was identified during
herbicide screening at the University of Georgia in Tifton. The objective...
The first objective of this paper is to prove the existence and uniqueness of global solutions for
a Kirchhoff-type wave equation with
nonlinear dissipation of the form Kuⁿ + 𝑀(|𝐴¹/²𝑢|²)𝐴𝑢 + 𝑔(𝑢')=0 under suitable
assumptions on 𝐾, 𝐴, 𝑀(⋅), and 𝑔(⋅). Next, we under some growth conditions on the nonlinear...
We derive the fundamental solution of the linearized problem of the motion of a viscous uid around a rotating body when the axis of rotation of the body is not parallel to the velocity of the uid at infinity.
The electrochemical intercalation of tetra-n-alkylammonium (TAA) cations into graphite is investigated using galvanostatic reduction and cyclic voltammetry in TAABr/ dimethylsulfoxide (DMSO) electrolytes. Structural and compositional analyzes by X-ray diffraction, thermogravimetric and elemental analyzes show that stable graphite intercalation compounds (GICs) are formed with highly-flattened TAA cation bilayers for (C₅H₁₁)₄N⁺, (C₆H₁₃)₄N⁺,...
The physical, biological, chemical, and optical
processes of the ocean operate on a wide
variety of spatial and temporal scales, from
seconds to decades and from micrometers to
thousands of kilometers (Dickey et al., this
issue; Dickey, 1991). These processes drive
the accumulation and loss of living and nonliving
mass...
The particulate optical backscattering coefficient (bbₚ) is a
fundamental optical property that allows monitoring of marine suspended
particles both in situ and from space. Backscattering measurements in the
open ocean are still scarce, however, especially in oligotrophic regions.
Consequently, uncertainties remain in bbₚ parameterizations as well as
in satellite estimates...
This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...
High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
Given two rational maps φ and ψ on Ρ¹ of degree at least two, we study a symmetric, nonnegative real-valued pairing〈φ, ψ〉which is closely related to the canonical height functions hφ and hψ associated to these maps. Our main results show a strong connection between the value of〈φ, ψ〉and the...
One of the most persistent questions regarding the phase equilibria of mid-ocean ridge basalts (MORB) pertains to the petrogenesis of the anorthitic plagioclase phenocrysts (>An₉₀) that are characteristic of the more primitive members of such suites. Anorthitic phenocrysts are present in many if not most MORB suites in spite of...
Steepland valleys subject to debris flows incise bedrock even as episodic deposition typically covers valley bottoms. This paper’s hypothesis is that, while continual fluvial processes evacuate deposits, storage of episodic deposition drives valley widening and, thereby, creation of accommodation space for sediment storage on the valley floor. Data from three...
We used an in situ steady state ¹⁵N-labeled nitrate (¹⁵NO₃⁻) and acetate (AcO⁻) well-to-wells injection experiment to determine how the availability of labile dissolved organic carbon (DOC) as AcO⁻ influences microbial denitrification in the hyporheic zone of an upland (third-order) agricultural stream. The experimental wells receiving conservative (Cl⁻ and Br)...
We undertook an interlaboratory comparison of techniques used to extract and analyze trapped gases in ice cores. The intercomparison included analyses of standard reference gases and samples of ice from the Greenland Ice Sheet Project 2 (GISP2) site. Concentrations of CO₂, CH₄, the δ¹⁸O of O₂, the δ¹⁵N of N₂,...
The defect mechanisms that underpin the high energy density dielectric 0.8BaTiO₃–0.2Bi(Zn₁/₂Ti₁/₂) O₃
were investigated. Characterization of the nominally stoichiometric composition revealed the
presence of a Ti³⁺-related defect center, which is correlated with lower resistivities and an
electrically heterogeneous microstructure. In compositions with 2 mol. % Ba-deficiency, a barium
vacancy-oxygen vacancy...
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online 28 September 2012)
[http://dx.doi.org/10.1063/1.4757256]
This article was originally published
The defect mechanisms that underpin the high energy density dielectric 0.8BaTiO₃–0.2Bi(Zn₁/₂Ti₁/₂) O₃
were investigated. Characterization of the nominally stoichiometric composition revealed the
presence of a Ti³⁺-related defect center, which is correlated with lower resistivities and an
electrically heterogeneous microstructure. In compositions with 2 mol. % Ba-deficiency, a barium
vacancy-oxygen vacancy...
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dielectric properties of BaTiO3
canbe manipulated through doping or through the formation
of solid
Chromosomal rearrangements may complicate construction of Arabidopsis with multiple TDNA-insertion mutations. Here, crossing two lines homozygous for insertions in AtREV3 and AtPOLH (chromosomes I and V, respectively) and selfing F1 plants yielded non-Mendelian F2 genotype distributions: frequencies of +/++/+ and 1/1 2/2 progeny were only 0.42 and 0.25%. However, the...
Chromosomal rearrangements may complicate construction of Arabidopsis with multiple TDNA-insertion mutations. Here, crossing two lines homozygous for insertions in AtREV3 and AtPOLH (chromosomes I and V, respectively) and selfing F1 plants yielded non-Mendelian F2 genotype distributions: frequencies of +/++/+ and 1/1 2/2 progeny were only 0.42 and 0.25%. However, the...
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mitosis into two
nuclei, whose presence defines the gametophyte to beat stage 3-II. Thus, ovules
from
A mixed initial and boundary value problem is considered for
a partial differential equation of the form Muₜ(x, t)+Lu(x, t)=0,
where M and L are elliptic differential operators of orders 2 m
and 2l, respectively, with m ≤ l. The existence and uniqueness
of a strong solution of this equation...
Chromosomal rearrangements may complicate construction of Arabidopsis with multiple TDNA-insertion mutations. Here, crossing two lines homozygous for insertions in AtREV3 and AtPOLH (chromosomes I and V, respectively) and selfing F1 plants yielded non-Mendelian F2 genotype distributions: frequencies of +/++/+ and 1/1 2/2 progeny were only 0.42 and 0.25%. However, the...
Restricted rotations of chemical bonds can lead to the presence of persistent conformational chirality in molecules 10 lacking stereocenters. We report the development of first-ofa- kind predictive rules that enable identification of conformational chirality and prediction of racemization barriers in the diarylether heptanoid (DAEH) natural products that do not possess...
Microglia and reactive astrocytes accumulate in the spinal cord of rats expressing the Amyotrophic lateral sclerosis (ALS)-linked SOD1ᴳ⁹³ᴬ mutation. We previously reported that the rapid progression of paralysis in ALS rats is associated with the appearance of prolifer- ative astrocyte-like cells that surround motor neurons. These cells, designated as Aberrant...
We have measured voltage-current characteristics for YBa₂Cu₃O₇ thin films in magnetic fields from 5
T to ambient, including some in the millitesla range. In all cases, the resistivity —current density isotherms
can be separated into two classes: those which exhibit upward curvature, and have constant
resistivity at low currents, and...
Lead-free ceramics of composition Bi(Mg₁/₂Ti₁/₂)O₃-(Bi₁/₂K₁/₂)TiO₃-(Bi₁/₂Na₁/₂)TiO₃ were prepared
using solid state synthesis techniques. The dielectric spectra showed a Tmax of more than 320 °C
for all compositions, and the transitions became increasingly diffuse as the Bi(Mg₁/₂Ti₁/₂)O₃
content increased. A lower temperature transition, indicating a transformation from an ergodic to a
non-ergodic...
Refractive indices of In₂O₃, In₂₋ₓSnₓO₃, InBO₃ and 2 different gahnite crystals (ZnAl₂O₄ and Zn.₉₅Fe.₀₅Al₂O₄) were measured at wavelengths of 435.8 to 643.8 nm and were used to calculate n at λ = 589.3 nm ( nD ) and at λ = ∞ (n∞) using the one-term Sellmeier equation 1/(n²-1) =...
The solid solutions of InGa₁₋ₓFeₓCuO₄, InFeCu₁₋ₓMgₓO₄, and InGa₁₋ₓFeₓCu₁₋ₓMgₓO₄ were
synthesized and characterized through the use of X – ray and neutron diffraction, and DC –
magnetism measurements. All compositions of InGa₁₋ₓFeₓCuO₄ are single phase and crystallize
in the R3m space group, but a transformation to the spinel InFeMgO₄ structure was...
The defect mechanisms that underpin the high energy density dielectric 0.8BaTiO₃–0.2Bi(Zn₁/₂Ti₁/₂) O₃ were investigated. Characterization of the nominally stoichiometric composition revealed the presence of a Ti³⁺-related defect center, which is correlated with lower resistivities and an electrically heterogeneous microstructure. In compositions with 2 mol. % Ba-deficiency, a barium vacancy-oxygen vacancy...
SEE ARTICLE FOR ABSTRACT IN SPANISH. English Abstract: In order to study the quantitative relationship between tuber yield of two potato (Solanum tuberosum L.) cultivars (‘Alpha’, susceptible, and ‘Zafiro’, moderately resistant to late blight), and severity of the pathogen in Toluca, México, managed by weekly foliar sprays of 0.575 kg...
Empirical algorithms for the total absorption coefficient and absorption
coefficient by pigments for surface waters at 440 nm were developed by applying a quadratic formula that combines two spectral ratios of remote-sensing reflectance. For
total absorption coefficients ranging from 0.02 to 2.0 m⁻¹, a goodness of fit was achieved
between...
The propagation of downwelling irradiance at wavelength l from surface to a depth (z) in the ocean is governed by the diffuse attenuation coefficient, K𝒹(λ). There are two standard methods for the derivation of K𝒹(λ) in remote sensing, which both are based on empirical relationships involving the blue-to-green ratio of...
Biogenic opal, organic carbon, organic matter stable isotope, and trace metal data from
a well-dated, high-resolution jumbo piston core (EW0408–85JC; 59° 33.3′N, 144° 9.21′W,
682 m water depth) recovered from the northern Gulf of Alaska continental slope reveal
changes in productivity and nutrient utilization over the last 17,000 years. Maximum...
We investigated the late-time (asymptotic) behavior of tracer test breakthrough
curves (BTCs) with rate-limited mass transfer( e.g., in dual-porosity or multiporosity
systems) and found that the late-time concentration c is given by the simple expression
C = tₐ𝒹{C₀g-- [m₀(∂g/∂t)]}, for t >> tₐ𝒹 and tα >> tₐ𝒹, where tad is...
Biogeochemical reactions associated with stream nitrogen cycling, such as
nitrification and denitrification, can be strongly controlled by water and solute residence
times in the hyporheic zone (HZ). We used a whole‐stream steady state ¹⁵N‐labeled
nitrate (¹⁵NO₃⁻) and conservative tracer (Cl⁻) addition to investigate the spatial and
temporal physiochemical conditions controlling...
We have measured cosmic ray produced ¹⁰Be (t₁/₂ = 1.5 My) and ²⁶Al (t₁/₂ = 0.72 My) as functions of depth in a core of quartz sandstone bedrock collected in South Victoria Land, Antarctica. These data were used to place limits on the exposure age and erosion rate of the...
The northern spotted owl (Strix occidentalis caurina) is one of the most intensively studied raptors in the world; however, little is known about the impacts of wildfire on the subspecies and how they use recently burned areas. Three large-scale wildfires in southwest Oregon provided an opportunity to investigate the short-term...
The synthesis of isoindazoles bearing α-ketoester and α-hydroxyester groups via the coarctate cyclization of ester terminated azo-ene-yne precursors is described. Whereas previous studies on isoindazole formation have shown the reaction to proceed through a kinetic coarctate pathway, functionalization of the terminal acetylene with a methyl ester sufficiently stabilizes the carbene...
The initial-value problem is studied for evolution equations in Hilbert space of the general form d/dt A(u) + B(u) ϶ f, where and are maximal monotone operators. Existence of a solution is proved when A is a subgradient and either is strongly monotone or B is coercive; existence is established...
"In this paper, we use community-level data from Oregon’s 234 rural communities, which we define as incorporated cities with less than 50,000 people, to analyze Federal forest policy. We hypothesize that positive policy impacts due to amenity-related migration were confined to nearby communities, while the negative impacts due to mill...