This dissertation explores the engineering of carbon nanotube electronic devices using atomic force microscopy (AFM) based techniques. A possible application for such devices is an electronic interface with individual biological molecules. This single molecule biosensing application is explored both experimentally and with computational modeling.
Scanning probe microscopy techniques, such as...
Carbon Nanotubes are a unique family of nanostructures that have shown remarkable promise for mechanical, electrical, and optical applications. Fundamentally similar to the earlier discovered Buckminsterfullerene (C₆₀), carbon nanotubes are hollow cylinders formed from a single sheet of carbon atoms. The research presented in this dissertation investigates several carbon nanotube...
A continuous, low-velocity, nearly monochromatic atomic beam is created using
laser cooling and two-dimensional magneto-optic trapping. Rubidium atoms from an
effusive oven are slowed and cooled using Zeeman-tuned slowing. The scattering force
from a counter-propagating, frequency-stabilized diode laser beam is used to decelerate
the thermal beam of atoms to a...
More that just magnificent views of atoms and
molecules, Scanning Tunneling Microscopy, STM, images have
the potential to answer some fundamental questions relating
to surface molecular dynamics and bonding characteristics of
localized species versus more common analytical tools that
provide average of bulk sample information. A special
feature of the...
A new experimental technique for the study of
atom-surface interactions is obtained by passing an atomic
beam containing high-Rydberg states through a fine mesh
target. The technique is demonstrated to be a sensitive
probe of the electric fields of adsorbed dipole layers in
transmission experiments in which a time-dependent beam...
Semiconducting materials are of immense importance due to their presence in almost all modern devices. It is possible that the surface physics of semiconductors could be used to control the nanoscale topography and properties of these materials, ultimately creating new options for device fabrication. This could result in profound implications...
Cells in three-dimensional (3D) environments exhibit very different biochemical and biophysical phenotypes compared to the behavior of cells in two-dimensional (2D) environments. As an important biomechanical measurement, 2D traction force microscopy can not be directly extended into 3D cases. In order to quantitatively characterize the contraction field, we have developed...
A low velocity, low temperature beam of atoms is produced
from a two-dimensional magneto-optic trap known as an atomic
funnel. The funnel provides simultaneous spatial and velocity
compression of atoms and will provide a source for a three-grating
atomic interferometer. Rubidium atoms from an oven are slowed
by chirped cooling...
A procedure for evaluating the precision of atomic absorption
measurements is presented and applied to 21 elements under varying
instrumental conditions. The experimental relative standard deviations
(RSD's) in absorbance obtained from repetitive measurements made
with a high resolution voltmeter and on-line computer, are compared
to those predicted by a recently...
The variable length, six-electrode plasma source for atomic
emission spectroscopy described here is operated from three
compact, simple, and inexpensive direct current power supplies. The
vertical arcs formed between the three electrode pairs completely
entrain the sample and are typically operated at 40 V and 20 A.
Three concentric quartz...
As scaling of silicon (Si) based devices approaches fundamental limits, thin film metal-insulator-metal (MIM) tunnel diodes are attracting interest due to their potential for high speed operation. Because operation of these devices is based on tunneling, electrode / interfacial roughness is critical. Recently, it was shown that combining ultra-smooth bottom...
Nucleation in atomic layer deposition (ALD) determines how many cycles are required to initiate growth and to form a continuous film. Nucleation has been exploited for the formation of nanoparticles, catalysts, and for area-selective ALD. Although sometimes overlooked or misrepresented in ALD reports, nucleation is also critical for multicomponent ALD...
Plasma sources with multiple electrodes have been developed and
characterized in this research for atomic emission spectroscopy.
Multi-electrode plasma sources use electrodes to shape the plasma in
order to continuously entrain a sample stream in the center of hot
plasma, in a manner similar to an inductively coupled plasma (ICP)...
One taphonomic problem plaguing archaeologists and physical anthropologists, whether their research is in North American cultures or hominid sites in Africa, is the difficulty in distinguishing bone altered by burning and heating from bone altered by soil processes. Archaeologists working to understand the recent prehistory of the Southern Oregon Coast...
Atomic layer deposition (ALD) is an enabling technique for many new micro- and nanoscale technologies. The self-limiting surface chemical reactions by which ALD fundamentally operates give rise to uniquely high precision (atomic) control over deposited film thickness, uniformity over large areas, and conformality over complex and extreme topographies. One such...
Back end of line (BEOL) metal-insulator-metal capacitors (MIMCAPs) have become a core passive component in modern integrated circuits. International Technology Roadmap for Semiconductors (ITRS) projections for scaling of analog/mixed-signal MIMCAP applications require simultaneously increasing capacitance density while maintaining low leakage current density and low voltage nonlinearity (characterized by the quadratic...
This work entails both imaging and therapeutic applications of biomedical optics. In both contexts, an understanding of light transport in tissues is necessary. An overview of optical transport in tissues is given, including scattering theory. Digital Fourier holographic microscopy is introduced and applied as a means of metrology via optical...
The amorphous to crystalline phase change is of great interest for the production and operation of phase change memory and germanium electronic devices. Phase change memory relies on the ability to differentiate between differences in optical or electrical properties between the amorphous and crystalline phases of a single material. Amorphous...
The general theme of this dissertation is the application of novel carbon based micro sensors with the scanning electrochemical microscopy (SECM). SECM allows positioning of the probe without touching the substrate while mapping the chemical parameters in 3D space above the substrate. The main focus of the dissertation is the...
Dental plaque is one of the well-characterized biofilms in the human body. Oral bacterial species play vital roles in maintaining healthy bacterial homeostasis as well as causing oral infections. Many of the oral diseases are caused by opportunistic pathogens, and therefore, the bacterial metabolic activities become important in dictating their...
We present a report on a new capability for low temperature microscopy of organic
optoelectronic semiconductor materials. We may now perform photoluminescence (PL) and
conductivity measurements as a function of temperature on a microscopic level.
Testing confirmed the setup's ability to support microscopic measurements at pressures
of 10^-6 Torr and...
This paper describes the construction and use of a cost-effective custom-built atomic layer deposition (ALD) system, as well as the investigation of aluminum oxide atomic layer deposition using trimethylaluminum and water. For this research, a cost-effective ALD system was constructed for less than $8,000 using existing parts that were given...
Two-dimensional transition metal dichalcogenides (TMDs) have recently come under intense investigation as building blocks for van der Waals heterostructure electronics. One of the most promising TMDs is MoS₂, which transitions from an indirect bandgap (1.3 eV) in its bulk state to a direct band gap (1.8 eV) in its single...
The phases of transition alumina are scientifically interesting due to their high specific surface area, favorable acid/ base characteristics, and chemical and hydrothermal stability which make this metallic oxide a prime candidate for use as a support for metallic nanoparticles (NPs) in heterocatalysis. Interactions at alumina/Pt interfaces are important for...
The work presented in this thesis deals with the mechanisms by which a vibrationally excited diatomic molecule gives up its energy to a host monatomic lattice at low temperature. The vibrational lifetimes (v"=1) of the metal oxides Ba0 and A10 in their ground electronic states are studied using pulsed dual...
Phase change memory materials are a set of chalcogenide or pnictogenide materials systems currently being researched for use in optical and resistive based memory systems due to their large change in optoelectronic properties between the amorphous and the crystalline states. For these materials systems to be considered as a suitable...
Current methods in traction force analysis rely on a homogeneous extra-cellular matrix and
embedded microbeads to track deformations. The efficacy of these methods decreases when the matrix is not homogeneous. In heterogeneous matrices, beads often aggregate in regions of higher matrix density and float in regions where matrix substrate is...
On August 6, 1945 the United States of America dropped an atomic bomb
on the city of Hiroshima, Japan. Three days later another atomic bomb was
dropped on the city of Nagasaki, Japan. The events that led up to the United
States' decision to drop the atomic bombs on Japanese...
The atomic solid state energy (SSE) scale is introduced as a tool for inorganic materials design. The SSE scale is obtained by assessing an average electron affinity (EA) (for a cation) or an average ionization potential (IP) (for an anion) for each atom using data from compounds having that specific...
This thesis includes three studies involving different aspects of modeling protein structure. The first study illustrates the levels of insight available from atomic-resolution protein structures. The second study derives general trends of protein geometry from atomic-resolution structures and shows their implications for modeling. The third study creates a model of...
This article presents a novel method combining ion irradiation, in-situ transmission electron microscopy (TEM), and microchemistry analysis before/after irradiation, which allows to examine same microstructural areas throughout ion irradiation. A 12 wt% Cr Ferritic/Martensitic steel (HT9) was irradiated in the TEM to 1.17 x 10(20) ions.m(-2) at 440 degrees C...
Metal-insulator-metal (MIM) tunnel devices have been proposed for high speed applications such as hot electron transistors, IR detectors, optical rectennas for IR energy harvesting, and backplanes for LCDs. The majority of these applications require highly asymmetric and non-linear current versus voltage (I-V) behavior at low applied voltages and ultra-high frequencies....
We investigated the thermal stability of a new ternary amorphous metal thin film, Ta₂.₄Ni₂.₂Si, and assessed its suitability as a Cu diffusion barrier for semiconductor device applications. Transmission electron microscopy was coupled with atom probe tomography to provide a detailed understanding of the atomic-scale evolution of both structure and composition...
The self-interstitial defect is commonly regarded as important in regulating diffusion
in silicon. A review of the literature reveals that the scientific bases for invoking the
self-interstitial defect are weak, while an alternate defect, the vacancy cluster, has been
largely ignored. One argument which has been used to establish dominance...
A sensitive technique for the determination of As(III) and As{V)
at μ/L and sub-μg/L concentrations from a single sample aliquot
has been developed. This technique is based on the hydride
generation atomic absorption (HGAA) spectrophotometry. The hydrides
of the arsenic species are generated in a reaction vessel by mixing
the...
Graphite oxides which had been prepared from three different
size graphite particles by the modified Brodie method were observed
with the electron microscope. The thermal decomposition products
of the oxides, obtained by heating them at 240° and 300°,
were observed using the electron microscope and x-ray diffraction.
Graphite oxide was...
Pollen, the male product of the flower, is a crucial component in plant reproduction, as it transmits the sperm cells to the female structures, enabling fertilization and subsequent seed production. A major transition of the pollen life cycle, triggered upon pollination of female floral tissue, is from a dormant pollen...
The objectives of this study were to 1) develop a relatively quick staining procedure that would detect incipient decay by color differentiation under fluorescence, 2) quantitatively assess the amount of decay present with the use of an image analyzer, and 3) re/ate loss in strength at various decay levels to...
Low temperature atomic layer deposition (ALD) of monolayer to few layer MoS₂ uniformly across 150mm diameter SiO₂/Si and quartz substrates is demonstrated. Purge separated cycles of MoCl5 and H₂S precursors are used at reactor temperatures of up to 475 °C. Raman scattering studies show clearly the in-plane (E¹₂g) and out-of-plane...
Bismuth oxide thin films were deposited by atomic layer deposition using Bi(OCMe₂ [superscript i]Pr)₃ and H₂O
at deposition temperatures between 90 and 270°C on Si₃N₄, TaN, and TiN substrates. Films were
analyzed using spectroscopic ellipsometry, x-ray diffraction, x-ray reflectivity, high-resolution
transmission electron microscopy, and Rutherford backscattering spectrometry. Bi₂O₃ films
deposited...
Cellulose nanocrystal (CNC) aerogels are coated with thin conformal layers of Al₂O₃ using
atomic layer deposition to form hybrid organic/inorganic nanocomposites. Electron probe
microanalysis and scanning electron microscopy analysis indicated the Al₂O₃ penetrated more
than 1500 μm into the aerogel for extended precursor pulse and exposure/purge times. The
measured profile...
The corrosion and passivity of iron (and carbon steel) in media with different alkalinity as well as iron depassivation have been studied extensively using electrochemical methods and nano-scale surface characterization studies. The electrochemical techniques provide valuable information about the average electrochemical behavior of relatively large metal surfaces, typically in centimeter-square...
Two-phase flow in helical conduits is important in many industries where reaction between components, heat transfer, and mass transport are utilized as processes. The helical design is chosen for the effects of secondary flow patterns that reduce axial dispersion, increased heat transfer, and also their compact design. The first is...
A high volume sampling system, employing Nuclepore filters and
designed for sampling particulate in the plumes from industrial
sources using a light aircraft, is described. The effluent of kraft
paper mills was sampled using this system and then analyzed by
electron microscopy.
Size distributions of particles were obtained at several...
The classic treatment of diffusion by Einstein and by Chandrasekhar assumed
conservative boundary conditions; mobile species were neither created nor destroyed
on the sample surface. It is normal to assume that vacancies and host interstitials are
created and annihilated on incoherent interfaces or free surfaces; i.e., these are
assumed to...
Transparent conductive oxides (TCOs), primarily indium doped tin oxide, have been widely used in numerous fields since decades ago, such as solar cells, displays, OLEDs and ‘smart windows’ etc. Owing to the scarcity of indium, there is a great demand for new alternative materials. Metal/insulator/metal (MIM) diodes are a critical...
A comparison was made of Al₂O₃ films deposited on Si via prompt inorganic condensation (PIC)
and atomic layer deposition (ALD). Current–voltage measurements as a function of annealing
temperature indicate that the solution-processed PIC films, annealed at 500°C, exhibit lower
leakage and roughly equivalent breakdown strength in comparison to ALD films....
In the first part of this work, thin films of Al₂O₃ deposited via atomic layer deposition (ALD) are demonstrated to improve the thermal stability of cellulose nanocrystal (CNC) aerogels. ALD is a chemical vapor deposition (CVD) like method in which sequential precursor exposures and self-limited surface reactions produce a conformal...
The atomic age was enacted by many scientists as a way to realize health and human rights. Human rights were conceived in this context as rights to economic development, science education, and nuclear medicine. The United States Atomic Energy Commission (AEC) acted hand in hand with UN agencies and educators...
France’s decision to test their nuclear weapons program in the Sahara in 1960 wholly reshaped how the Cold War infiltrated into West Africa. During a time of nation building, Ghanaian President Kwame Nkrumah urged Ghana and Africa, more broadly, to break ties with colonial powers and rebuke further attempts of...
A computer simulation program, which runs efficiently on
micro-computers, for the diffusion of point defects in the diamond
and zincblende structure was developed. The simulated point
defects comprise vacancies, host or impurity interstitials on any
of three types of interstitials sites, and impurities. Diffusion
via vacancy first and second neighbor...
A thermal beam of lithium atoms excited to high Rydberg states
by pulsed electron impact has been studied by time-of-flight analysis.
Near the end of a 35-cm field-free flight path, the excited atoms pass
through a pair of electric field plates before entering an excited-atom
detector. Electric field ionization was...
The temporal and spatial characteristics of a laser microprobe plume were investigated using the spectroscopic methods of emission, absorption and fluorescence. The plume was produced by rapid vaporization of a small quantity (1 μg) of a solid sample using a focussed pulsed dye laser (110 MW/cm²). For absorption and fluorescence...
Using a simple dry transfer process, I construct and characterize three nanoscale MoS2 devices using current-voltage curves, Raman spectroscopy, optical and atomic force microscopy. I compare these devices, the thinnest of which was few layer ( ≤ 10 nm) MoS₂ capable of showing photoconductance, with a current whose magnitude is...
Using a low-energy, three stage, differentially pumped ion
accelerator, similar to that used by Hagstrom for Auger electron
ejection studies, permits, with the application of radiotracer methods,
a new approach to the study of low energy sputtering.
The experimental approach consisted of pumping down the
experimental tube to 10⁻⁹ torr,...
Cancer is a hard disease to control because of its ability to spread to different parts of the body. Cancer cells can spread out from a primary tumor to distant organs which gives rise to new cancer cell colonies and more tumors over time. This process is known as metastasis...
The energy barrier heights between two recently reported Ta-based amorphous metals (TaWSi and TaNiSi), TaN, and atomic layer deposited Al2O3 and HfO2 insulators are measured in metal/insulator/metal (MIM) structures with Au top electrodes using internal photoemission (IPE) spectroscopy. For Al2O3, the Ta-based metal barrier heights, phi(Bn), increase with increasing metal...
Molybdenum disulfide (MoS₂) field effect transistors (FET) were fabricated on atomically smooth large-area single layers grown by chemical vapor deposition. The layer qualities and physical properties were characterized using high-resolution Raman and photoluminescence spectroscopy, scanning electron microscopy, and atomic force microscopy. Electronic performance of the FET devices was measured using...
Development of long-range nuclear weapons in recent years and
the subsequent threat of nuclear war has led to an increased awareness
of the need for civilian protection. Adequate shelter design can
provide substantial protection against delayed radioactive fallout.
Protection can generally be greatly increased by more massive roof
construction to...
The objective of this paper is to demonstrate a method for mechanically characterizing a 25 μm thick elastoviscoplastic hemodialysis membrane and for quantifying the force required to use that membrane in compression sealing. First, methods are developed for mechanically characterizing the thin elastoviscoplastic membrane. Then, a finite element model is...
The microscopic, momentum space, optical potential description of spin 1/2 x 1/2 scattering is extended to include the coupling of the singlet-triplet spin channels and
the exact handling of the Coulomb force. Computing performance in constructing
the optical potential and in solving the coupled-channels Lippmann-Schwinger equations
is enhanced by parallelization...
Investigations of plasma production by a pulsed dye laser
microprobe were made. Comparisons between a Q- switched and a
pulsed dye laser system were made on the intensity of the continuum
produced by atmospheric breakdown. The dye laser system was
foundtominimize the production of the continuum which in turn
allowed...
Nanoparticles, materials on a 10⁻⁹ meter size scale, are finding applications in
a variety of areas including catalysts, fuel and solar cells, biological labeling.
electronics and optoelectronic devices. Semiconductor nanoparticles are of particular
interest because of their size tunable properties resulting from quantum confinement
effects. Mass productions of monodisperse semiconductor...
Since a NanoSIMS high-resolution secondary ion mass spectrometry instrument was first used for cosmochemistry investigations over a decade ago, both interest in NanoSIMS and the number of instruments available have significantly increased. However, SIMS comes with a set of challenges that are of both technical and conceptual nature, particularly for...
The ultimate properties of a fibrous composite system depend highly on the transverse mechanical properties of the fibers. Here, we report the size dependency of transverse elastic modulus in cellulose nanocrystals (CNCs). In addition, the mechanical properties of CNCs prepared from wood and cotton resources were investigated. Nanoindentation in an...
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
This thesis presents the results of quantum-mechanical first principles calculations
of optical, electronic and mechanical properties of organic molecules and solids, which have
diverse potential applications such as photovoltaics, flexible electronics, and mechanical
catalysts with applications in force sensors and self-healing materials.
The electronic and optoelectronic properties of organic thin...
In this dissertation, the structure and electronic properties of multiple metal oxide thin films are characterized and presented. Prompt inorganic condensation (PIC) of metal-oxo and –hydroxo clusters was evaluated as a technique for making metal oxide clusters in two separate studies. The first focuses on the synthesis of lithium niobate...
Digital printing techniques offer several advantages in manufacturing electronics such as direct writing of materials, reduction of chemical waste, and scalability. In particular, printing can significantly simplify manufacturing processes by directly defining the channel area, the gate, and the source and drain contacts, allowing for lower costs and higher throughput...
Carbon nanotubes (CNTs) are grown using plasma enhanced chemical vapor deposition (PECVD). A modified radio frequency (RF) parallel-plate plasma etching system serves as the growth reactor. The effects of process parameters, including temperature, pressure, and C2H2:NH3 ratio, are studied. CNTs are grown on glass substrates with Al underlayers and Ni...
Microchannel devices are rapidly evolving process technology with a wide variety of applications. Microchannel devices hold the potential to transform many separation processes. One potential application for such microchannel devices is kidney dialysis. By reducing the size and cost of the device, this technology offers the potential to allow dialysis...
There is a continual interest in developing robust, flexible, durable, lightweight, waterborne polymer barrier coatings which are increasingly resistant towards both chemical warfare agents as well as an ever growing number of toxic industrial chemicals. In this study, barrier films were prepared with poly(vinyl alcohol) (PVOH) and varying amounts of...
In a search for designed materials that mimic those found in biological systems, combining polymers with inorganic materials in sol-gel chemistry processes has gained momentum in the research world since the 1990's. This work methodically investigated the properties of several related polymer-SiO₂ hybrids prepared by a simple methodology that could...
This objective of this study is to investigate the capability of nanostructured surfaces on dissipating heat flux by performing pool boiling and convective flow boiling. The generation of ultra-high heat flux from high performance electric devices has motivated a number of investigations related to advanced heat transfer especially in two-phase...
Phosphate and peroxide stabilize new oxo-hydroxo niobium clusters in water at low pH. The clusters open a new chapter in aqueous niobium chemistry under acidic conditions. The clusters also produce atomically smooth, amorphous niobium oxide phosphate (NbPOx) thin films. Reaction pathways from cluster solutions to amorphous niobium oxide phosphate solids...
Radiation damage caused by fission fragments to metal surfaces is an important research topic. Thin titanium foils were irradiated with a continuous wave beam of 132 MeV ¹³²Xe+²⁹ at the current intensity of 2 pnA. Pre- and post-irradiated surface topologies were investigated using atomic force microscopy and the observed defects...
The fabrication of nano-scale devices is a challenging, but potentially important, technology that has drawn a great deal of interest among researchers. Such nanoscale constructions utilizing a bottom-up approach for device building have many foreseeable applications in areas as diverse as miniaturized electronics, sensors, and biomedical devices.
One of the...
Thin films of the p-type semiconductor, barium copper sulfide fluoride (BaCuSF) were deposited using pulsed laser deposition. Similar p-type conductivity in Cu2O is caused by copper vacancies. Addition of copper dopant is proposed as a method for filling the copper vacancies in BaCuSF. The films are characterized to determine quality...
The objective of this thesis is to provide an initial demonstration of two-terminal and three-terminal electronic devices employing amorphous multi-component metallic film
(AMMF) electrodes. Such a demonstration is successfully achieved in the fabrication of metal-insulator-metal (MIM) diode and hot electron transistor (HETs) structures employing ZrCuAlNi AMMF electrodes. The ultra-smooth surface...
Two different doping techniques, oxygen intercalation and Mg cation
substitution, were investigated in thin film p-type CuScO₂, a wide band gap
semiconductor with the delafossite structure. Films rf-sputtered onto amorphous SiO₂
substrates were polycrystalline after post-deposition annealing. X-ray diffraction was
used to determine that the films are predominantly polycrystalline 3R...
Atomic Layer Deposition (ALD) is a promising technique for the production of
biologically safe, wear resistant and corrosion protective coatings for orthopedic
applications. In this work, the impact of coating thickness and surface preparation on the
hardness (H), elastic modulus (E), wear resistance, and delamination of ALD Al2O3 films
is...
Atomic Layer Deposition (ALD) is a promising technique for the production of
biologically safe, wear resistant and corrosion protective coatings for orthopedic
applications. In this work, the impact of coating thickness and surface preparation on the
hardness (H), elastic modulus (E), wear resistance, and delamination of ALD Al2O3 films
is...
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elastic modulus close to that of bone.
Atomic layer deposition (ALD) is a common method applied for the
Polyethylene has been used extensively for natural gas transport since the mid-1970's. The pipeline system is sound and well-functioning, but there are some aspects of the system that could be improved. One of these is the repair method of leaking pipes. Presently if a natural gas pipe begins to leak,...
A study of the effect of catalyst properties on the synthesis of carbon nanotubes (CNTs) is done in this thesis. Three different metal alloy catalysts, Fe/Ti, Ni/Ti, Co/Ti, have been studied. Various atomic concentrations and thicknesses were cosputter deposited on clean Si wafers using AJA Orion 4 RF Magnetron sputter...
Recent studies have indicated that nickel gallium alloys can be effective for the catalytic hydrogenation of CO2 to methanol. To simplify the characterization of NiGa catalysts, we are developing model systems using NiGa thin films. We prepared NiGa thin films by RF magnetron sputtering using an equiatomic alloy target, followed...
Metal-organic frameworks (MOFs) represent an exciting, new class of porous materials. Their hybrid organic-inorganic structure opens up near infinite possibilities to tune and design their structure for specific properties and applications. A new generation of flexible MOFs, following a generation of stiff MOFs, has created additional design space and complexity....
Optimized processing conditions for
Pt/TiO₂/SiO₂/Si templating electrodes were investigated. These
electrodes are used to obtain [111] textured thin film lead
zirconate titanate (Pb[ZrₓTi₁₋ₓ]O₃ 0≤x≤1) (PZT). Titanium
deposited by dc magnetron sputtering yields [0001] texture on a
thermally oxidized Si wafer. It was found that by optimizing
deposition time, pressure, power,...
Metal-oxo clusters are discrete, soluble pieces of bulk metal oxide. Cluster size, monodispersity, and chemical properties allow for potential use as solution-based precursors for functional metal oxide films. Classical monoalkyltin-oxo clusters are either charge neutral or stabilized by anions. The structure of Cs₄.₅H₂.₅[(BuSn)₃(α-SiW₉O₃₇)]*2H₂O enables its use in established ion exchange...
Integrase catalyzes insertion of a retroviral genome into the host chromosome. Following reverse transcription, integrase binds specifically to the ends of the duplex retroviral DNA, endonucleolytically cleaves two nucleotides from each 3'-end (the processing activity), and inserts these ends into the host DNA (the joining activity) in a concerted manner....