Data centers have been charged a great amount of electric bill by the power company and demand charge can contribute up to 40% of the electric bill due to the "random" workload. This phenomenon can be avoided by using the existing Uninterrupted Power Supply (UPS) as the assistant power source...
In the past decades, femtosecond stimulated Raman spectroscopy (FSRS) has been gaining tremendous popularity in fundamental sciences stemming from chemistry to biology. It is capable of capturing both equilibrium and non-equilibrium structural information across a broad range of timescales with simultaneously high temporal and spectral resolutions. Femtosecond transient absorption spectroscopy...
Compactness in deep learning can be critical to a model’s viability in low-resource applications, and a common approach to extreme model compression is quantization. We consider Iterative Product Quantization (iPQ) with Quant-Noise [Fan et al., 2020] to be state-of-the-art in this area, but this quantization framework suffers from preventable inference...
Advances in deep learning based image processing have led to their adoption for a wide range of applications, and in tow with these developments is a dramatic increase in the availability of high quality datasets. With this comes the need to accelerate and scale deep learning applications in order to...
Various natural language processing (NLP) tasks necessitate deep models that are fast, efficient, and small based on their ultimate application at the edge or elsewhere. While significant investigation has furthered the efficiency and reduced the size of these models, reducing their downstream latency without significant trade-offs remains a difficult task....
County governments in the United States play important roles in the tax collection and public service provisions. Thus, a better understanding of the local government finances is closely related to the welfares of residents. In this dissertation, I provide two essays: in the first essay, I examine the fiscal impacts...
In this dissertation, I describe the experimental investigation of catching ions in superfluid helium droplets. The ultimate goal of our project is to build a coherent electron diffraction apparatus for atomic structure determination from oriented single macromolecules. This involves generating protein ions from electrospray ionization (ESI) and doping them in...
Fluorescence spectroscopy is a powerful analytical technique due to bright signals that provide excellent measurement sensitivity. Many colors of fluorescent dyes are available to match the detection ranges of different equipments. Dyes can be chemically modified to bind to many different target analytes with high specificity1. Alternatively, sensors can be...
Ultrafast spectroscopy can exploit the structure-function relationship of chemical- and biological-based systems. More specifically, femtosecond stimulated Raman spectroscopy (FSRS) provides ground- and excited-state vibrational information with simultaneously high spectral (spatial) and temporal resolutions. The electronic counterpart, femtosecond transient absorption (fs-TA), complements FSRS data analysis as part of a comprehensive approach...
Ultrafast spectroscopy has recently gained momentum as a powerful, noninvasive characterization toolset capable of studying a diverse array of samples with applications in chemistry, physics, biology, engineering, and more. Two popular ultrafast spectroscopic techniques include femtosecond transient absorption (fs-TA) and femtosecond stimulated Raman spectroscopy (FSRS). The latter of these techniques...
Photoactivated biomedical tools like fluorescent biosensors and optogenetic proteins have increased in popularity due to the precision targeting and activation used for in vivo applications. In nature, the initially discovered parent proteins exhibit properties such as fluorescence quantum yield (FQY), fluorescence color, and photoswitching dynamics that are unfavorable in mammalian...
:
_____________________________________________________________________
Chong Fang
“The journey of 1000 miles begins with a single step.” – Miyamoto Musashi
In this thesis, I present a new method we developed to study low frequency (< 700 cm⁻¹) vibrational dynamics: Time-resolved third-harmonic generation (TRTHG) spectroscopy. Among a variety of vibrational spectroscopy techniques, TRTHG differentiates itself with robustness, versatility, and simplicity. In TRTHG experiment, that involves only two ultrashort laser pulses, the...
In this dissertation, excited state proton transfer (ESPT) and its inhibition in solution and protein environments are revealed using both femtosecond transient absorption (fs-TA) spectroscopy and femtosecond stimulated Raman spectroscopy (FSRS). Using a tunable Raman pump to enhance transient vibrational features of the photoacidic chromophore HPTS in methanol and methanol...
Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast vibrational technique which allows rapid collection of Raman spectra with simultaneously high temporal and spectral resolution. With the recent development of FSRS methodology, three FSRS techniques (conventional, tunable, and anti-Stokes) have been implemented in our laboratory to dissect the excited state structural...
To obtain a mechanistic understanding of the chemical processes, techniques that offer a frame-by-frame visualization of molecular structure during a reaction are of vital importance. Numerous efforts and advances have been made in order to acquire such vivid molecular “movies”, especially in the electronic excited state. Ultrafast molecular spectroscopy method...
Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
Fluorescent proteins have emerged as an essential toolset for bioimaging, creating a demand for engineering proteins with new and improved fluorescent properties. In this thesis, I explore the atomistic structure of REX-GECO1, a newly engineered protein biosensor that has unique optical properties. Since this protein has no available crystal structure,...
In this dissertation, my research work on excited state dynamics of small organic molecules in solutions is presented. Using femtosecond stimulated Raman spectroscopy (FSRS) as the main experimental tool, the excited state hydrogen-bonding dynamics (ESHBD) of Coumarin 102, a common laser dye molecule, in ethanol solution is examined with <150...
Resonance enhancement has been increasingly employed in the emergent femtosecond stimulated Raman spectroscopy (FSRS) to selectively monitor molecular structure and dynamics with improved spectral and temporal resolutions and signal-to-noise ratios. Such joint efforts by the technique- and application-oriented scientists and engineers have laid the foundation for exploiting the tunable FSRS...
Accurate chromosome segregation and cell cleavage are critical to maintaining genomic integrity. Both events involve the spindle apparatus, but the exact mechanics is as puzzling as the contradicting models proposed in the last two centuries. In this dissertation, current prevailing models of chromosome segregation and cell cleavage are tested using...
Full Text:
DISSERTATION OF
Wei Chen for the degree of Doctor of Philosophy in Zoology presented on
March 21, 2007
The ever-increasing environmental degradation in China is leading people to pay more attention to environmental protection. Although Chinese government has made progress in dealing with environmental problems, the environment still gets worse. Thus, ordinary people began to take part in environmental issues, and make contributions to environmental protection. With increased...
Taiwan has undergone significant social change, particularly in the last forty years, due to economic and industrial growth. Career development intervention is increasingly urgent in helping students face upcoming challenges. This study investigates the implementation and perceived helpfulness of career development interventions in Taiwanese comprehensive high schools. A total of...
The major purpose of this study was to determine if there were differences between well-trained pre- adolesents and untrained, but normally active counterparts in physical working capacity , body composition and blood lipids. The study hypotheses were that the trained subjects would have a lower mean body fat percentage, lower...
The harmonic problem in power systems is gaining more attention as incidences correlated with harmonics increase. Conventional passive filtering techniques for harmonic mitigation have inherent problems, and purely active filters have the disadvantages of higher costs and ratings. Hybrid active filters inherit the efficiency of passive filters and the improved...
Hibiscus and lilacs (Syringa spp.) are economically important nursery crops in the US that accounted for 4.5 million units ($30 million) and 2 million units ($20 million), respectively (USDA, 2016). To maintain and expand the market share of ornamental plants such as lilacs and Hibiscus, novel performance, floral ornamental value,...
Vibriosis caused by the bacterial pathogen Vibrio tubiashii is one of several factors contributing to mass larval mortalities of the Pacific oyster (Crassostrea gigas) in Pacific Northwest shellfish hatcheries in recent years. Genetically improved strains of the Pacific oyster resistant to V. tubiashii would be highly desirable. This study investigates...
Delta-Sigma (ΔΣ) analog-to-digital converters (ADCs) are widely used in wireless transceivers. Recently, continuous-time (CT) ΔΣ ADCs gain growing interest in wireless applications for their lower power consumption and wider input bandwidth as compared with the discrete-time (DT) counterparts.
In this thesis, a wideband low-power CT ΔΣ modulator for next generation...
The objectives of this project were to investigate the critical factors impacting the physicochemical and antibacterial properties of β-chitosan based films derived from jumbo squid (Dosidicus gigas) pens, and to evaluate the feasibility of improving water solubility of β-chitosan through Maillard reaction. The studies examined the effect of molecular weight...
The success of NIKE, Inc. is deemed miracle by professionals on both Wall
Street and Madison Avenue. Research done in the past tends to credit the growth
of NIKE, Inc. to its marketing strategies. By placing the achievement of the
company in the postmodern context, this study analyzes the cultural...
Coniferous trees are a major North American crop that has been intensively managed for its commercial value, while also serving as critical habitat for abundant wildlife and as carbon sinks. Having diverse functions, North American temperate coniferous forests have become a research hotspot for numerous scientific studies aiming to integrate...
This work investigates a methodology for estimating the ocean stratification gradient based on high-resolution, in space and time, remote sensing observations of internal wave propagation speeds. The internal wave speed observations were collected using a shore-based, X-band marine radar and the ocean vertical density profiles were collected simultaneously from an...
Direct sequence spread spectrum (DSSS) was initially used for anti-jamming in military applications and was later developed in other commercial applications. Walsh codes, which are a set of mutually orthogonal codes, are one type of the spreading codes used in DSSS systems. For any spreading codes of length N, these...
Characterizing the hydrophobicity of nanoparticles can help us understand their fate and transport in the environment, as well as how nanoparticles may interact with biological systems. However, contact angle and partition coefficient have limitations in measuring the hydrophobicity of nanoparticles, thus promising methods to measuring the hydrophobicity of nanoparticles are...
Digital printing techniques offer several advantages in manufacturing electronics such as direct writing of materials, reduction of chemical waste, and scalability. In particular, printing can significantly simplify manufacturing processes by directly defining the channel area, the gate, and the source and drain contacts, allowing for lower costs and higher throughput...
Recently, continuous-time ΔΣ modulators are appearing increasingly often in both the literature and the marketplace due to their features of inherent antialiasing and relaxed requirements for opamp and so on. However, several nonideal factors such as clock jitter, excess loop delay, inter-symbol interference and so on, degrade the SNR performance...
A copula is the representation of a multivariate distribution. Copulas are used to model multivariate data in many fields. Recent developments include copula models for spatial data and for discrete marginals. We will present a new methodological approach for modeling discrete spatial processes and for predicting the process at unobserved...
Wine volatile composition is one of the most important constitutes of wine quality, and it is greatly influenced by number of factors. The studies herein were conducted to evaluate the grape and wine aroma affected by different vine nutrient status, vigor and crop levels of Oregon Pinot noir.
In the...
This study first investigated the developmental changes in the volatile composition and carotenoids of Pinot noir grapes. Grape berries were sampled every week from pea size to harvest during the 2011 and 2012 season. Carotenoids and organic acids were analyzed by HPLC. Volatile compounds were extracted from crushed berries using...
It is often perceived that late maturity of grape gives a more complex aroma
profile to Pinot noir wine, however, there is little understanding of the basic flavor
chemistry of grape maturity on wine aroma. The aroma contributing compounds in
Pinot noir were first identified by aroma extract dilution analysis...
The time-domain simulation of wave-structure
interactions using the finite element method is presented
in this study. Combined initial and boundary value
problems for diffraction and radiation of waves by large
structures are posed. Linearized free surface boundary
conditions are used, but motions of the structural
boundaries compared to the wave...
Remote sensing forest inventory gained increased attention in the last decade triggered by the decrease in the price of sensors and the explosion of data availability and formats. Evermore, the constant advances in the hardware processing the data emphasized the necessity to develop algorithms to extract forest relevant information from...
The research explored in this thesis helps provide a better understanding of efforts that have been undertaken to more precisely calculate environmental impacts and human health risks, such as energy consumption, carbon footprint, and toxicity, to support environmental sustainability assessment of products. The work is comprised of two research objectives,...
Oxides are a versatile class of materials with a wide range of electronic, optical, and magnetic properties. This makes them ideal for use in a multitude of functional devices for oxide electronics, electrochemical conversion, and storage. The overall performance of these devices is governed by atomic scale charge and mass...
The scarcity of wireless spectrum resources and the overwhelming demand for wireless broadband resources have prompted industry, government agencies and academia within the wireless communities to develop and come up with effective solutions that can make additional spectrum available for broadband data. As part of these ongoing efforts, cognitive radio...
As the power system grows larger and more complex, real-time monitoring and control become very significant in order to achieve reliable operation of the power system. Before any security assessment can be made or control actions are taken, the reliable estimate of the existing state of the system must be...
Phytophthora sojae is an oomycete pathogen of soybean. As a result of its economic importance, P. sojae has become a model for the study of oomycete genetics, physiology and pathology. The lack of efficient techniques for targeted mutagenesis and gene replacement have long hampered genetic studies of pathogenicity in Phytophthora species....
Developmental changes in the carotenoids and volatile compounds of Pinot noir grape berries were investigated in this study from pea size to harvest during 2012. HPLC analysis showed continued decrease of lutein, β-carotene, neochrome a and neoxanthin continued to decrease during berry development, with rapid decrease of lutein and (9′z)-neoxanthin...
Aroma potentials in early and late maturity Pinot noir grapes were investigated in two
consecutive vintages. The grape samples were hydrolyzed under acidic conditions and the
released odorants were studied by aroma extract dilution analysis (AEDA). Forty-nine
main odor-active compounds were detected in the AEDA. The odorants released with
high...
Nanoparticles are a hugely diverse category of material that have a wide variety of biomedical applications, and developing tools for biological research with high cellular uptake is critical to their effective application. However, rarely is attention paid to the exact mechanism by which this is occurring, with most studies focusing...
We strategically modified the GFP core via chemical synthesis to make redder and brighter biomimetic fluorophores. Based on quantum calculations, solvatochromism analysis, and femtosecond Raman, we unveiled the additive effect of tuning the electronic ground and excited states, respectively, to achieve a dramatic emission redshift with a "double-donor-one-acceptor" structure.
In this paper, a Direction of Arrival (DOA) based system is proposed. This method searches the direction relative to the array to find where the signal source is located. The proposed system can achieve sub-meter level accuracy with a near real-time update rate. Also, we introduced several refinement methods including...
As one of the most popular data types, the point cloud is widely used in various appli- cations, including computer vision, computer graphics and robotics. The capability to directly measure 3D point clouds is invaluable in those applications as depth information could remove a lot of the segmentation ambiguities in...
Besides enabling an enhanced mobile broadband access, fifth-generation (5G) wireless mobile networks are envisioned to support the connectivity of massive, heterogeneous Internet of Things (IoT) devices. Connecting these devices through 5G systems and providing them with their needed data rates require huge amounts of spectrum and power resources, thus calling...
The bimolecular reaction of two carbenoid species resulting in the formation of a carbon-carbon double bond (pi-system), referred to herein as carbenoid eliminative cross-coupling (CEXC), involves a series of three fundamental steps: (i) ate-complex formation (transmetalation), (ii) 1,2-metalate rearrangement, and (iii) beta-elimination. All three steps are stereospecific and so the...
The objectives of this study are to 1) qualitatively and quantitatively measure the odor-active compounds in ‘Marion’ blackberry; 2) compare the aroma profiles of advanced selections and new cultivars of thornless blackberry cultivars with ‘Marion’; 3) study the development of furaneol in ‘Marion’ during ripening and; 4) investigate the distribution...
The post-translational modification of proteins by electrophilic oxylipids is emerging as an important mechanism that contributes to the complexity of proteomes. Enzymatic and non-enzymatic oxidation of biological lipids results in the formation of chemically diverse electrophilic carbonyl compounds, such as 2-alkenals and 4-hydroxy alkenals, epoxides and eicosanoids with reactive cyclopentenone...
Full Text:
detection and identification
Yury V. Vasil’ev, Shin-Chen Tzeng, Lin Huang and Claudia S. Maier
We demonstrate the generation of broadband up-converted multicolor array (BUMA) in a thin BK7 glass slide using two noncollinear weak near-IR laser pulses with various crossing angles. The BUMA signal arises from cubic nonlinear χ⁽³⁾:χ⁽³⁾ processes via cascaded four-wave mixing of the two incident beams. Broad and continuous tunability of...
All-optical switching has myriad applications in optoelectronics, optical communications, and
quantum information technology. To achieve ultrafast optical switching in a compact yet versatile
setup, we demonstrate distinct sets of two-dimensional (2D) broadband up-converted multicolor
arrays (BUMAs) in a thin type-I β-barium-borate crystal with two noncollinear near-IR
femtosecond pulses at various...
Perfluorooctanesulphonicacid (PFOS) is an organic contaminant that is ubiquitous in the environment, wildlife, and humans. Few studies have assessed the effects of chronic PFOS exposure on central nervous system function in aquatic organisms. The present study defined the behavioral effects of varying life span chronic exposures to low dose PFOS...
To determine how well DNA barcodes from the chloroplast region perform in forest dynamics plots
(FDPs) from global CTFS-ForestGEO network, we analyzed DNA barcoding sequences of 1277 plant
species from a wide phylogenetic range (3 FDPs in tropics, 5 in subtropics and 5 in temperate zone)
and compared the rates...
Full Text:
, D. L., Chen, B., Ge, X., Mi, X., Swenson, N. G., ... & Kress, W.
J. (2015). Closely-related taxa
To determine how well DNA barcodes from the chloroplast region perform in forest dynamics plots
(FDPs) from global CTFS-ForestGEO network, we analyzed DNA barcoding sequences of 1277 plant
species from a wide phylogenetic range (3 FDPs in tropics, 5 in subtropics and 5 in temperate zone)
and compared the rates...
Full Text:
Nancai Pei
1,2*
, David L. Erickson
3
, Bufeng Chen
1,2
, Xuejun Ge
4
, Xiangcheng Mi
5
, Nathan G
Tethering fluorophores on metal nanoparticles for metal enhanced fluorescence (MEF) has attracted a lot of attention from scientists interested in fluorescence based approaches. MEF has many benefits in fluorescence related techniques, because the analytical signal increases and enables potentially lower detection limits or better sensitivity. Many types of nanoparticles have...
The grand plan of carbon neutralization and COP26 in Glasgow require a quick shift of energy sources from conventional fossil fuel to a more renewable substitute such as wind, or solar energy. However, the intermittency of those renewable energy sources does not meet the demand of the energy, which requires...
Electrochemical capacitors and batteries are two major electrochemical energy storage technologies, which have been investigated extensively to meet the rapidly-growing demand for higher energy, higher power, lower cost and enhanced safety in the past few decades. With the charge storage mechanism of electrostatic charge adsorption desorption via electrical double layers,...
Biological hydrogen production from renewable feedstocks was reckoned as a promising method for sustainable energy production. Bioelectrochemical hydrogen production using microbial electrolysis cells (MECs) demonstrated superiorities over the conventional methods for hydrogen production. The introduction of the membrane-less single chamber design further improved the feasibility of MECs for practical application,...
A unique microreactor-assisted nanomaterial synthesis and printing process was studied for the fabrication of patterned metal oxide nanostructured thin films. The process uses a continuous flow microreactor to control and generate a reactive chemical flux that was transported to a patterned microfluidic channel. The microreactor-assisted nanomaterial synthesis process can generate...
Nanostructured ZnO films were obtained via thermal oxidation of thin films formed with metallic Zn-nanoparticle dispersions. Commercial zinc nanoparticles used for this work were characterized by microscopic and thermal analysis methods to analyze the Zn-ZnO core shell structure, surface morphology and oxidation characteristics. These dispersions were spin-coated on SiO₂/Si substrates...
The microbial communities play a crucial role in maintaining human health and cause diseases through very complex microbial chemical interactions. Therefore, these microbial communities have drawn much attention to the scientific communities. To elucidate these complex microbial communities and the chemical interactions within it, one or more isolated species of...
In this dissertation, I present experimental observations of multiply charged atomic ions (MCAI) generated from interactions of atomic/molecular clusters with moderately intense nanosecond laser pulses. This process is also known as Coulomb explosion (CE) and it has been extensively studied in intense laser fields using ultrashort pulses. Several prevailing theories...
In this dissertation, I describe the experimental investigation of large superfluid helium droplets. The goal and direction of this thesis is to facilitate the use of these droplets as part of our project ss-EDI. The overall scheme of ss-EDI is to dope proteins inside helium droplets and collect a diffraction...
Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
Oxidative stress is defined as an imbalance that favors the production of reactive oxygen species (ROS) over an organism's antioxidant defense. ROS have the ability to damage, either directly or indirectly, biomolecules including DNA, proteins, carbohydrates, and lipids. Various pathological conditions and environmental and chronic diseases have been associated with...
In this dissertation, I describe the experimental investigation of electron diffraction of neutral and ionic clusters doped into superfluid helium droplets. The project is aimed at contributing to the development of an overall approach called ‘serial single molecule electron diffraction imaging (ss-EDI), a potential approach to solve macromolecule structures bypassing...
CuInGaSe₂ (CIGS), a promising thin film solar cell material, has gained lots of
attention in decades due to its high energy conversion efficiency and potential lower
manufacture cost over conventional Si solar cells. As a cheaper processing method
compared to vacuum-based techniques, solution-based deposition has been
successfully applied to fabricate...
Hub proteins bind a large number of partners to facilitate structural changes and downstream protein interactions. LC8, a highly conserved protein homodimer, is a unique hub that regulates the activity of proteins in a wide range of cellular processes by binding to intrinsically disordered regions. With many of these systems,...
This work introduces a new methodology to design transportation fuels offering improved efficiency and reduced emissions, aimed to complement both traditional and emerging engine technologies. Many of these emerging technologies are centered around exploiting low temperature combustion (LTC) strategies that offer improved efficiency and reduced emissions. However, a standardized fuel...
Advancing the understanding of natural resource management is an important step in mitigating the effects of human activity on the environment, and ensuring efficient outcomes for many sectors of the economy. As humanity’s role in the natural world becomes better understood, the importance of interdisciplinary modeling has grown in leaps...
Coherent phonon dynamics in condensed-phase medium are responsible for important material properties including thermal and electrical conductivities. We report a structural dynamics technique, time-resolved surface third-harmonic generation (TRSTHG) spectroscopy, to capture transient phonon propagation near the surface of polycrystalline CaF₂ and amorphous borosilicate (BK7) glass. Our approach time-resolves the background-free,...
Intracellular pH (pH(i)) imaging is of paramount importance for life sciences. In this work, we implement the ultrafast electronic and stimulated Raman spectroscopies to unravel the fluorescence mechanism of an excitation-ratiometric pH(i) indicator in basic aqueous solution. After photoexcitation of the pH(i) indicator HPTS, a hidden charge-transfer (CT) state following...
We achieve a series of distinct broadband third-harmonic generation (THG) signals at the amorphous glass–air interface attributed to third-order and cascaded third-order nonlinear processes. A novel THG laser sideband arises
from cascaded interaction between fundamental pulses and the cascaded four-wave mixing signals. The spatially
separated THG sidebands with distinct spectral...
Simulation of local atmospheric flows around complex topography is important for several applications in wind energy (short term wind forecasting and turbine siting and control), local weather predictions in mountainous regions and avalanche risk assessment. However atmospheric simulation around steep mountain topography remains challenging and there exist several way to...
Femtosecond stimulated Raman spectroscopy (FSRS) is an emerging molecular structural dynamics technique for functional materials characterization typically in the visible to near-IR range. To expand its applications we have developed a versatile FSRS setup in the ultraviolet region. We use the combination of a narrowband, ~400 nm Raman pump from...
To determine how well DNA barcodes from the chloroplast region perform in forest dynamics plots (FDPs) from global CTFS-ForestGEO network, we analyzed DNA barcoding sequences of 1277 plant species from a wide phylogenetic range (3 FDPs in tropics, 5 in subtropics and 5 in temperate zone) and compared the rates...
Zoxamide is the sole β-tubulin inhibitor registered for the control of oomycete pathogens. The current study investigated the activity of zoxamide against Phytophthora sojae and baseline sensitivity was established with a mean EC₅₀ of 0.048 μg/ml. The data is critical for monitoring changes in zoxamide-sensitivity in the field. Three stable...
Full Text:
: 20 May 2016
Citation:
Cai M, Miao J, Song X, Lin D, Bi Y,
Chen L, Liu X and Tyler BM (2016)
C239S
We demonstrate a surface enhanced Raman scattering (SERS) substrate by integrating plasmonic-active SiO₂ nanotubes into Si₃N₄ gratings. First, the dielectric grating that is working under guided mode resonance (GMR) provides enhanced electric field for localized surface plasmon polaritons on the surface of metallic nanoparticles. Second, we use SiO₂ nanotubes with...
Stripe rust is a foliar disease of wheat (Triticum aestivum L.) caused by the air-borne fungus Puccinia striiformis f. sp. tritici and is present in most regions around the world where commercial wheat is grown. Breeding for durable resistance to stripe rust continues to be a priority, but also is...
Full Text:
, Essex, England, pp 376
Fang T, Garland-Campbell KA, Liu Z, Chen XM, Wan A, Li S, Liu
Z, Cao S, Chen Y
Biosensors have become an indispensable tool set in life sciences. Among them, fluorescent protein-based biosensors have great biocompatibility and tunable emission properties but their development is largely on trial and error. To facilitate a rational design, we implement tunable femtosecond stimulated Raman spectroscopy, aided by transient absorption and quantum calculations,...
Tracking vibrational motions during a photochemical or photophysical process has gained momentum, due to its sensitivity to the progression of reaction and change of environment. In this work, we implemented an advanced ultrafast vibrational technique, femtosecond-stimulated Raman spectroscopy (FSRS), to monitor the excited state structural evolution of an engineered green...
Gene regulation by small RNA pathways is ubiquitous among eukaryotes, but little is known about small RNA pathways in the Stramenopile kingdom. Phytophthora a genus of filamentous oomycetes, contains many devastating plant pathogens, causing multibillion-dollar damage to crops, ornamental plants, and natural environments. The genomes of several oomycetes including Phytophthora...
The level of reactive oxygen species (ROS) is tightly regulated in biological systems as overproduction can lead to oxidative stress and result in a number of diseases. Due to its negative effects, antioxidants are studied and used against ROS in medicine, pharmaceuticals and therapeutics. Because of issues with the uptake...
Heterogeneous catalytic reactions in solvents are important for chemical processes like direct methanol fuels, biomass conversion to biofuels and electrochemical reduction of CO2 to fuels. Numerous experimental studies have shown that co-adsorbates and solvents affect the rate and selectivity of heterogeneous catalytic reaction, therefore fundamental understanding of how co-adsorbates and...
Bisphenol A (BPA), a high-volume chemical used to make polycarbonate plastic and epoxy resins, is a ubiquitous contaminant in environment and human body. To investigate the reproductive effects of long-term exposure to low concentrations of BPA, a two-generation study was conducted using the aquatic model species of zebrafish. Our findings...
As a persistent organic contaminant, perfluorooctanesulphonic acid (PFOS) has been widely detected in the environment, wildlife, and humans. The present study revealed that zebrafish embryos exposed to 16 µM PFOS during a sensitive window of 48-96 hour post-fertilization (hpf) disrupted larval morphology at 120 hpf. Malformed zebrafish larvae were characterized...
Full Text:
zebrafish organogenesis
Chen, J., Tanguay, R. L., Tal, T. L., Gai, Z., Ma, X., Bai, C., ... & Dong, Q
In 2005, Beijing acted to court the farmers of Taiwan through a series of unilateral
agricultural tariff reductions. This move was deliberately formulated to weaken the incumbent
Democratic Progressive Party (DPP) by targeting the party's strong rural base. This paper seeks
to investigate the effectiveness of China's use of interest...
Abstract: Background: Exposure to pollutants including metals and particulate air pollution can alter DNA methylation. Yet little is known about intra-individual changes in DNA methylation over time in relationship to environmental exposures. Therefore, we evaluated the effects of acute-and chronic metal-rich PM[subscript 2.5] exposures on DNA methylation.
Methods: Thirty-eight male...